MICRO AND NANO R2R EMBOSSING OF EXTRUDED POLYMERS

This dissertation presents a process for directly imprinting or embossing extruded polymers as an advancement in roll-to-roll (R2R) embossing methods that avoids the problems of converting preformed films, increases throughput, and reduces costs. A proof-of-concept R2R apparatus was designed and constructed for directly embossing extruded polymer, and experimental results were evaluated. This laboratory scale R2R apparatus employed a thin metal ribbon belt mold with micro or nano scale features in a calendering setup, with a close coupled induction heating (IH) coil to preheat the ribbon mold above glass transition temperature (Tg) of the polymer, prior to contact with the extrudate at the nip of the calender. This allowed the melted polymer to fully fill the mold patterns before starting to solidify. The thin ribbon mold rapidly conducted heat to the calender roller, providing an effective cooling stage. Microscale and nanoscale features were imprinted directly onto extruded polymer film at a rate of 10 to 12 meters per second, three to over one hundred times the throughput of current R2R processes and orders of magnitude faster than planar processes. Metal ribbon mold belts with nano features were needed to test the direct embossing of extruded polymers at the nano scale. Three different avenues were taken to make such ribbon belts. First, preset nickel alloy molds were obtained. A master mold of the Book of Leviticus with letters 6 µm in width, 6 to 9 µm tall and 60-170 nm high and a nickel alloy DVD master mold with track pitch of 740 nm and 105 nm deep Pits between 400 nm and 1900 nm long. These were welded into stainless steel ribbon belts to form belt molds. Second, a process was developed using base forms or mandrels for metal-forming nickel ribbon belt molds with test patterns that included gratings from 70 to 500 nm and pillars having diameters of 1 µm, 700 nm, 500 nm and 350 nm. Third, an investigation of metal glass (MG) as a candidate mold material was undertaken and a laboratory scale mechanism was designed and constructed to emboss metal glass surfaced rollers thermally

Coded Pulse Transmission and Correlation for Robust Ultrasound Ranging from a Long-Cane Platform

The objective of this research was to increase the independence and safety of the sight impaired by developing an enhanced travel aid in the form of a sensor embedded long-cane to reduce the risk of injury from walking into suspended or overhanging objects while providing the sight impaired community with a familiar and well accepted tool. Prior research at the Electromechanical Systems Laboratory had established a theoretical framework for ultrasound-based ranging and spatial obstacle localization from the moving reference frame of a long-cane. A prototype was implemented using analog threshold detection techniques. This research focused on a new approach. A coded pulse was transmitted and correlation techniques were used to identify echoes and determine time of flight. Compared to the prior effort this new approach was more sensitive, had greater noise immunity, and provide greater spatial resolution for obstacle detection. The first step in the coded pulse approach was to generate a transmit pulse with an embedded binary code that is highly distinguishable. A transmit pulse generated by phase modulating a 40 kHz carrier signal with a 13-bit Barker code word, with each bit consisting of 4 cycles of the 40 kHz carrier was used. Digitized representative echoes were used as reference vectors for correlation to account for the effect of the impulse responses of the transducers, the air, and the reflection, on the transmitted pulse. In a detection cycle, the coded pulse was transmitted, the A/D converters took 2600 samples at the 150 kHz sampling rate to capture any echoes from objects between 1 and 4 meters in front of the cane. The receiver data was cross-correlated with the stored echo image to find echoes in the received signal. The correlation peak positions from the upper receiver were then compared to the peak positions from the lower receiver and if they collaborated within the synthetic aperture, the range and height were calculated annunciation was made by a synthesized voice. The new obstacle detection system described above was designed and a prototype was constructed and embedded into the shaft of an 18 mm diameter body of a long cane

Impact of COVID-19 on cardiovascular testing in the United States versus the rest of the world

Objectives: This study sought to quantify and compare the decline in volumes of cardiovascular procedures between the United States and non-US institutions during the early phase of the coronavirus disease-2019 (COVID-19) pandemic. Background: The COVID-19 pandemic has disrupted the care of many non-COVID-19 illnesses. Reductions in diagnostic cardiovascular testing around the world have led to concerns over the implications of reduced testing for cardiovascular disease (CVD) morbidity and mortality. Methods: Data were submitted to the INCAPS-COVID (International Atomic Energy Agency Non-Invasive Cardiology Protocols Study of COVID-19), a multinational registry comprising 909 institutions in 108 countries (including 155 facilities in 40 U.S. states), assessing the impact of the COVID-19 pandemic on volumes of diagnostic cardiovascular procedures. Data were obtained for April 2020 and compared with volumes of baseline procedures from March 2019. We compared laboratory characteristics, practices, and procedure volumes between U.S. and non-U.S. facilities and between U.S. geographic regions and identified factors associated with volume reduction in the United States. Results: Reductions in the volumes of procedures in the United States were similar to those in non-U.S. facilities (68% vs. 63%, respectively; p = 0.237), although U.S. facilities reported greater reductions in invasive coronary angiography (69% vs. 53%, respectively; p < 0.001). Significantly more U.S. facilities reported increased use of telehealth and patient screening measures than non-U.S. facilities, such as temperature checks, symptom screenings, and COVID-19 testing. Reductions in volumes of procedures differed between U.S. regions, with larger declines observed in the Northeast (76%) and Midwest (74%) than in the South (62%) and West (44%). Prevalence of COVID-19, staff redeployments, outpatient centers, and urban centers were associated with greater reductions in volume in U.S. facilities in a multivariable analysis. Conclusions: We observed marked reductions in U.S. cardiovascular testing in the early phase of the pandemic and significant variability between U.S. regions. The association between reductions of volumes and COVID-19 prevalence in the United States highlighted the need for proactive efforts to maintain access to cardiovascular testing in areas most affected by outbreaks of COVID-19 infection

Computational study of collisions between O(P-3) and NO((2)Pi) at temperatures relevant to the hypersonic flight regime

Reactions involving N and O atoms dominate the energetics of the reactive air flow around spacecraft when reentering the atmosphere in the hypersonic flight regime. For this reason, the thermal rate coefficients for reactive processes involving O(P-3) and NO((2)Pi) are relevant over a wide range of temperatures. For this purpose, a potential energy surface (PES) for the ground state of the NO2 molecule is constructed based on high-level ab initio calculations. These ab initio energies are represented using the reproducible kernel Hilbert space method and Legendre polynomials. The global PES of NO2 in the ground state is constructed by smoothly connecting the surfaces of the grids of various channels around the equilibrium NO2 geometry by a distance-dependent weighting function. The rate coefficients were calculated using Monte Carlo integration. The results indicate that at high temperatures only the lowest A-symmetry PES is relevant. At the highest temperatures investigated (20 000 K), the rate coefficient for the ``O1O2+N`` channel becomes comparable (to within a factor of around three) to the rate coefficient of the oxygen exchange reaction. A state resolved analysis shows that the smaller the vibrational quantum number of NO in the reactants, the higher the relative translational energy required to open it and conversely with higher vibrational quantum number, less translational energy is required. This is in accordance with Polanyi`s rules. However, the oxygen exchange channel (NO2+O1) is accessible at any collision energy. Finally, this work introduces an efficient computational protocol for the investigation of three-atom collisions in general. (C) 2014 AIP Publishing LLC